Journal
SCIENCE ADVANCES
Volume 6, Issue 2, Pages -Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/sciadv.aay8361
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Funding
- DARPA [W31P4Q1310005]
- Energy Frontier Research in Extreme Environments (EFree) Center, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science [DE-SC0001057]
- Warsaw University of Technology
- Polish National Agency for Academic Exchange
- DoD HPCMP Open Research Systems [ACOMM35963RC1]
- European Research Council Advanced Grant ToMCaT
- DOE-NNSA's Office of Experimental Sciences
- NSF-Earth Sciences [EAR-1634415]
- Department of EnergyGeoSciences [DE-FG02-94ER14466]
- DOE Office of Science [DE-AC02-06CH11357]
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Carbon-based frameworks composed of sp(3) bonding represent a class of extremely lightweight strong materials, but only diamond and a handful of other compounds exist despite numerous predictions. Thus, there remains a large gap between the number of plausible structures predicted and those synthesized. We used a chemical design principle based on boron substitution to predict and synthesize a three-dimensional carbon-boron framework in a host/guest clathrate structure. The clathrate, with composition 2Sr@B6C6, exhibits the cubic bipartite sodalite structure (type VII clathrate) composed of sp(3)-bonded truncated octahedral C12B12 host cages that trap Sr2+ guest cations. The clathrate not only maintains the robust nature of diamond-like sp(3) bonding but also offers potential for a broad range of compounds with tunable properties through substitution of guest atoms within the cages.
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