4.4 Article

Blueberry-Peel-Derived Porous Carbon for High-Performance Supercapacitors: The Effect of N-Doping and Activation

Journal

CHEMISTRYSELECT
Volume 5, Issue 3, Pages 1029-1036

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201904820

Keywords

Activation; Biomass; Melamine; Porous carbon; Supercapacitor

Funding

  1. Shanghai Municipal Natural Science Foundation [17ZR1432200]
  2. Open Research Fund of State Key Laboratory of Structural Chemistry [20170014]
  3. Tongji University
  4. Young Thousand Talented Program

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Nitrogen-doped (N-doped) activated porous carbon has been successfully prepared, using blueberry peel (BP) as a carbon source and melamine as a nitrogen source through a simple and effective carbonization and activation process. The obtained ABP-1.5-700 (ABP-x-y, ABP: blueberry peel derived activated porous carbon; x: BP/melamine mass ratio; y: carbonization temperature), with a nitrogen doping content of 8.29 at % presented a maximum specific capacitance of 324.3 F g(-1) at a current density of 1 A g(-1) in 6 M potassium hydroxide (KOH) aqueous electrolyte. It also showed an excellent cycle stability about 99.9% retention after 20000 charge-discharge cycles. The assembled ABP-1.5-700-based symmetric capacitor displayed the value of the specific capacitance was 75 F g(-1) at 1 A g(-1) with a maximum energy density of 13.78 Wh kg(-1) and a power density of 661.25 W kg(-1) (0-1.15 V) in 6 M KOH electrolyte solution. The results showed that the porous carbon derived from blueberry peel presented a good potential for high performance supercapacitors.

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