Journal
CHEMISTRYSELECT
Volume 5, Issue 4, Pages 1349-1352Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201903963
Keywords
Acylation; Aromatic aldehydes; 1; 3-dihydroisobenzofurans; Heterogeneous catalyst; Iodoarenes
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Funding
- Department of Science and Technology-Science and Engineering Research Board (DST-SERB), New Delhi [EMR/2017/005312]
- MHRD
- UGC
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Aromatic acylation is an indispensable chemical transformation in organic synthesis in affording aryl ketones. In this manuscript, we have described the synthesis of aromatic ketones utilizing graphene oxide (GO) supported PdO nanoparticles (PdO/GO), as heterogeneous transition metal catalyst. The [Pd]-heterogeneous catalyst enabled the coupling between iodoarenes and aromatic aldehydes. The acylation was carried out by eliminating toxic CO gas as the source of the carbonyl. Further, practicality of this strategy was also demonstrated by fusing 1,3-dihydroisobenzofurans.
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