4.4 Article

Direct and Solvent-Free Oxidative Cleavage of Double Bonds in High-Oleic Vegetable Oils

Journal

CHEMISTRYSELECT
Volume 5, Issue 4, Pages 1396-1400

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201903516

Keywords

azelaic acid; hydrogen peroxide; oxidation; tungstic acid; vegetable oils

Funding

  1. MIUR [AIM1829571]

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An unprecedented direct oxidation of high-oleic triglycerides to produce azelaic glycerides has been carried out by using a catalytic system based on H2WO4/H2O2. The results are highly competitive with those reported so far for simpler feedstock: at low catalyst loading the oxidation proceeds with satisfactory yields also starting from a real waste oil matrix without any prior purification.

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