Journal
ACS ENERGY LETTERS
Volume 5, Issue 1, Pages 31-38Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.9b02048
Keywords
-
Categories
Funding
- Key Research and Development of Ministry of Science and Technology of China [2018YFE0202600]
- National Natural Science Foundation of China [51572183, 51772331]
- National Key Technologies RD Program [2018YFB1106000]
Ask authors/readers for more resources
Vanadium pentoxide (V2O5) is an attractive high-capacity cathode material for lithium-ion batteries but is limited by the poor structural stability. In this work, we report the synthesis and properties of a new lithium-ordered superstructure of Li0.0625V2O5 through controlled prelithiation treatment. Compared to VO5 square pyramids in a pure alpha-V2O5 structure, the distorted VO5 square pyramid in this superstructure imparts an intrinsic layer structure with improved stability, expanded c-plane spacing, as well as expansion in the a-axis. In the voltage range of 2.5-4.0 V vs Li/Li+, Li0.0625V2O5 nanobelts with lithium-ordered superstructures exhibit a specific capacity up to 215 mAh g(-1), ultrahigh cycling capability, and high rate capability. Cyclic voltammograms of lithium insertion into Li0.0625V2O5 nanobelts also demonstrate two new pairs of reversible pseudocapacitive peaks in addition to the ordinary peaks of Le insertion into the pure orthorhombic alpha-V2O5.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available