Journal
ACS ENERGY LETTERS
Volume 5, Issue 1, Pages 221-223Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.9b02573
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- Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences of the U.S. Department of Energy [DE-FC02-04ER15533]
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The strong binding between CsPbBr3 nanocrystals and methyl viologen induces a long-lived charge-separated state following band gap excitation with important implications in photocatalytic processes. The unusually long-lived bleaching of the CsPbBr3 excitonic peak in this case arises from the creation of a dipole with the hole residing in CsPbBr3 and the electron in the surface-bound methyl viologen moiety.
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