Journal
JOURNAL OF CO2 UTILIZATION
Volume 34, Issue -, Pages 522-532Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jcou.2019.08.004
Keywords
CO2 hydrogenation; Liquid fuel; Fe catalyst; Cu promoter; K promoter
Funding
- Next Generation Carbon Upcycling Project through the National Research Foundation (NRF) - Ministry of Science and ICT, Republic of Korea [2017M1A2A2043133]
- [2018-1st-8C-001]
Ask authors/readers for more resources
Understanding the origin of the high activity of Fe-Cu-K catalysts during CO2 hydrogenation for liquid hydrocarbon production is imperative. However, designing suitable catalysts for efficient power-to-liquid processes remains challenging. In this work, we determined how Cu and K modified the Fe structure and revealed the origin of their synergistic effect in promoting its catalytic performance during CO2 hydrogenation to long-chain hydrocarbons. Detailed analyses confirmed that K addition facilitated incorporation of Cu into the Fe bulk lattice and helped maintain either a metallic or carbide active phase during the reaction. Electronic structure calculations suggested that formation of Fe-Cu alloy facilitated CO2 hydrogenation, regardless of the reaction pathway. A series of scaling relations between C binding energies and other adsorbates suggested that the presence of K facilitated CO formation and C-C coupling reactions over the Cu and Fe driven catalysis, respectively. Hence, the coexistence of Cu and K in the Fe catalyst is essential for producing liquid hydrocarbons from CO2.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available