Synthesis and Surface Modification of TiO2-Based Photocatalysts for the Conversion of CO2

Among all greenhouse gases, CO2 is considered the most potent and the largest contributor to global warming. In this review, photocatalysis is presented as a promising technology to address the current global concern of industrial CO2 emissions. Photocatalysis utilizes a semiconductor material under renewable solar energy to reduce CO2 into an array of high-value fuels including methane, methanol, formaldehyde and formic acid. Herein, the kinetic and thermodynamic principles of CO2 photoreduction are thoroughly discussed and the CO2 reduction mechanism and pathways are described. Methods to enhance the adsorption of CO2 on the surface of semiconductors are also presented. Due to its efficient photoactivity, high stability, low cost, and safety, the semiconductor TiO2 is currently being widely investigated for its photocatalytic ability in reducing CO2 when suitably modified. The recent TiO2 synthesis and modification strategies that may be employed to enhance the efficiency of the CO2 photoreduction process are described. These modification techniques, including metal deposition, metal/non-metal doping, carbon-based material loading, semiconductor heterostructures, and dispersion on high surface area supports, aim to improve the light absorption, charge separation, and active surface of TiO2 in addition to increasing product yield and selectivity.