Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 9, Issue 2, Pages 192-196Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201900688
Keywords
asymmetric catalysis; heterocycles; lactonizations; organocatalysis; selenium
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Funding
- JSPS KAKENHI Grant [JP19 K05480]
- Cooperative Research Program of Network Joint Research Center for Materials and Devices [20191310]
- Asahi Glass Foundation
- Tokuyama Science Foundation
- Takahashi Industrial and Economic Research Foundation
- Shorai Foundation for Science and Technology
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The development of chiral selenium catalysts for asymmetric transformations has become a pre-eminent topic in the field of organocatalytic chemistry. Herein, we report the development of chiral bifunctional selenide catalysts bearing a hydroxy group and discuss their application to asymmetric bromolactonization reactions. The importance of the bifunctional design of chiral selenide catalysts for enantioselective bromolactonizations was clearly demonstrated in the present work.
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