Improved Hydrophobicity and Dimensional Stability of Wood Treated with Paraffin/Acrylate Compound Emulsion through Response Surface Methodology Optimization

Wood treatment was conducted by paraffin/acrylate compound emulsion. Response surface methodology (RSM) was applied for modeling and to determine the relationship between hydrophobicity and influencing factors. The results showed that the paraffin emulsion concentration and acrylate emulsion percentage had significant influences on water absorption (WA) and mass percentage gain (MG). The WA decreased obviously with increasing acrylate emulsion percentage. The correlation models for WA and MG showed a good prediction due to the straight-line distribution in the normal probability plot of residuals. The optimal conditions (5.57% paraffin emulsion concentration, 20% acrylate emulsion percentage, and 10 min treatment time) provided by RSM were acceptable for predicting the MG and WA. Compared to untreated (66 degrees) and paraffin emulsion treated wood (94 degrees), the wood treated by compound emulsion showed the highest water contact angle (133 degrees) and better dimensional stability. This could be ascribed to a synergistic effect (bulking effect and filling effect) provided by paraffin and acrylate, which could form a completely hydrophobic film in wood.