Journal
MRS COMMUNICATIONS
Volume 10, Issue 1, Pages 91-97Publisher
CAMBRIDGE UNIV PRESS
DOI: 10.1557/mrc.2020.7
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Funding
- Naval Surface Warfare Center - Dahlgren Division (NSWCDD) In-House Laboratory Independent Research (ILIR) program
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To investigate the manipulation of electromagnetic properties of two-dimensional materials, this effort characterizes charge transfer behavior of colloidal COF-5 (covalent organic framework) in the presence of various metal ions. A series of metal chloride compounds was introduced to COF-5 in solution and solid film phases and the interaction of the material with electromagnetic radiation was monitored across the visible region using electronic absorption spectroscopy. Notable changes were observed, quantified, and discussed for copper (II) chloride (CuCl2), chromium (III) chloride (CrCl3), and iron (III) chloride (FeCl3) with COF-5. Ligand-to-metal and metal-to-ligand charge transfer are explored as a possible mechanism for the observed electronic behaviors.
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