Journal
AIP ADVANCES
Volume 10, Issue 1, Pages -Publisher
AIP Publishing
DOI: 10.1063/1.5129351
Keywords
-
Funding
- Japan Society for the Promotion of Science [21550170]
- Grants-in-Aid for Scientific Research [21550170] Funding Source: KAKEN
Ask authors/readers for more resources
A grating-structured interface of a poly(3-hexylthiophene) (P3HT) and n-type [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM)-based bulk-heterojunction (BHJ) photovoltaic (PV) cell was designed and fabricated to obtain a desirable thickness distribution of the deposited bathocuproine (BCP) buffer layer to efficiently utilize its potentials. As a master mold of the grating-structure, a commercially available recordable digital versatile disc (DVD-R) substrate was employed. The grating-structured surface of the P3HT:PCBM layer was successfully produced by duplication from a poly(dimethylsiloxane) secondary mold using the spin cast molding technique. From morphological observations of the grating-structured surface covered with vapor-deposited BCP, we roughly estimated the ratio of the BCP thickness at walls to that at top and bottom regions to be similar to 0.5. The grating-type BHJ PV cell with a 5-nm-thick BCP layer exhibited the maximum power-conversion efficiency (eta(p)) of 3.51%. Compared with the conventional flat-type BHJ PV cell with a 20-nm-thick BCP layer, the performance of the grating-type BHJ PV cell with a 20-nm-thick BCP layer was remarkably improved, owing to the contribution of the wall side contact, which provides a lower-barrier path of the electrons toward the cathode through the thinner BCP layer. (c) 2020 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available