Journal
ADVANCED ENERGY MATERIALS
Volume 10, Issue 6, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201903292
Keywords
fullerene; hybrid interphase; lithium dendrite suppression; lithium metal batteries; magnesium; moisture resistance
Categories
Funding
- National Natural Science Foundation of China [21872058]
- Key Project of Science and Technology in Guangdong Province [2017A010106006]
Ask authors/readers for more resources
Li metal is an ideal anode material for rechargeable high energy density batteries, but its sensitivity to humid air and uncontrolled dendrite growth limit its practical applications. A novel hybrid interphase is fabricated to address these issues. This interphase consists of dense fullerene (C-60) and magnesium metal bilayers, which are deposited successively on lithium foil by vacuum evaporation deposition and contribute to moisture resistance and lithium dendrite suppression. Thanks to this dual-functional feature, the assembled cells with the modified anodes and commercial LiFePO4 cathodes exhibit long cycle life (>200 cycles) with high capacity retention (>98.5%). Moreover, even the modified anodes that are exposed to humid air (30% relative humidity) for over 12 h; the cells still deliver excellent performance, comparable to those without exposure. Such a unique hybrid interphase provides a new promising method for fabricating air-stable and dendrite-free lithium metal batteries.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available