Journal
WASTE MANAGEMENT
Volume 102, Issue -, Pages 561-568Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.wasman.2019.11.012
Keywords
Catalytic fast co-pyrolysis; Composite molecular sieve; Rice husk; Waste greenhouse plastic films; Bio-oil
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Funding
- National Natural Science Fund Program of China [51776042, U1361115]
- Scientific Research Foundation of Graduate School of Southeast University, China [YBPY1904]
- Program of China Scholarships Council [201806090028]
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Catalytic fast co-pyrolysis of waste greenhouse plastic films and rice husk over a hierarchical HZSM-5/MCM-41 catalyst was performed in an analytical Py-GC/MS. We evaluated the effect of pyrolysis temperature and the ratio of rice husk to waste greenhouse plastic films on the total peak area of condensable organic products and CO2. In order to evaluate synergy possibilities among the two feedstocks, we performed non-catalytic pyrolysis and catalytic fast pyrolysis of rice husk and waste greenhouse plastic films separately. In addition, we report results for the catalytic fast co-pyrolysis of the mixture rice husk and waste greenhouse plastic films. The maximum relative content of hydrocarbons from catalytic fast co-pyrolysis of rice husk and waste greenhouse plastic films is obtained at 600 degrees C. When the mass ratio of rice husk to waste greenhouse plastic films is 1:1.5, the relative content of hydrocarbons reaches a maximum (71.1%). The hierarchical micro-mesoporous composite molecular sieve used in this work has outstanding catalytic activity and increases the relative content of hydrocarbons. (C) 2019 Elsevier Ltd. All rights reserved.
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