Journal
TETRAHEDRON LETTERS
Volume 61, Issue 1, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.151355
Keywords
Aquilaria malaccensis; Malacinones A and B; 6/6/5 ring system; Cadinane-type sesquiterpenoids
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Funding
- Bio-Synergy Research Project of the Ministry of Science (Republic of Korea), ICT and Future Planning through the National Research Foundation of Korea [NRF-2012M3A9C4048796]
- Vietnam National Foundation for Science and Technology Development (NAFOSTED) [108.05-2019.07]
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Two novel cadinane-type sesquiterpenoids, named as malacinones A (1) and B (2), with an unprecedented tricyclic 6/6/5 ring system have been isolated from the agarwood of Aquilaria malaccensis. Their structures were elucidated by the various spectroscopic data (IR, MS, 1D, and 2D NMR) analysis and the absolute configurations were determined by the electronic circular dichroism (ECD) spectroscopic data analysis. A plausible biosynthetic pathway of malacinones A and B was proposed. (C) 2019 Elsevier Ltd. All rights reserved.
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