Journal
SYNTHESIS-STUTTGART
Volume 52, Issue 6, Pages 807-818Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690046
Keywords
N-heterocycles; isoindolinones; transition-metal catalysis; C-H functionalization; cascade reactions; cyclizations; coupling reactions
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Funding
- National Research Foundation of Korea (NRF) - Government of Korea (MSIP) [2012M3A7B4049644, 2018R1A2A2A05018392, 2014-011165]
- National Research Foundation of Korea [2018R1A2A2A05018392, 2012M3A7B4049644] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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This short review describes the recent progress made on transition-metal-catalyzed annulative couplings for the synthesis of 3-methyleneisoindolin-1-ones, which are useful intermediates for the synthesis of numerous alkaloids and can be often found in a wide range of natural products and pharmaceuticals. In particular, new one-pot multiple C-C/C-N bond-forming processes for the construction of the 5-methylenepyrrol-2-one nucleus of such compounds are summarized.
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