Journal
SYNLETT
Volume 31, Issue 3, Pages 290-294Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1691559
Keywords
desymmetrization; Diels-Alder reaction; Mukaiyama hydration; quaternary carbon; tertiary alcohol
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Funding
- Japan Society for the Promotion of Science (JSPS KAKENHI) [JP17H01523]
- Platform Project for Supporting Drug Discovery and Life Science Research (Basis for Supporting Innovative Drug Discovery and Life Science Research
- BINDS) from Japan Agency for Medical Research and Development (AMED) [JP19am0101099]
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We disclose our synthetic studies on bilobalide, which features a Diels-Alder reaction of a cyclic anhydride to form two contiguous quaternary carbon centers, desymmetrization of a symmetric diol, and construction of a cyclic acetal under acidic conditions with inversion of configuration at an allylic position.
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