Journal
RENEWABLE ENERGY
Volume 147, Issue -, Pages 275-283Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.renene.2019.08.141
Keywords
Sewage sludge; SO42-/Al2O3-SnO2; Biodiesel
Funding
- Beijing Natural Science Foundation [8172029]
- National Natural Science Foundation of China [51308538]
Ask authors/readers for more resources
Catalysts are critical materials for biodiesel production using sewage sludge feedstock. In this research, different SO42-/Al2O3-SnO2 catalysts were prepared and characterized. The catalysts prepared at different conditions were characterized through Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), NH3 temperature-programmed desorption (NH3-TPD), NH3 adsorption FT-IR, and TGA. Then, esterification/transesterification reaction was performed with the lipid extracted from sewage sludge to verify the activity of these catalysts. Results showed that the catalysts with n(Al):n(Sn) = 1:10 prepared by 79 wt% H2SO4 possessed the best physical properties with a large number of active catalytic sites, which led to the biodiesel yield of 73.3% (based on dried extracted crude fat) under the optimized reaction conditions at 130 degrees C as reaction temperature, 0.8 g as catalyst loading for lipids extracted from 10 g freeze-dried sludge, 4 h as reaction time. Catalysts characterization results showed that acidity, acid sites and Al/Sn molar ratio play an important role in the activity of catalysts. The thermal properties showed that 450 degrees C was the suitable calcination temperature for catalyst preparation. The optimized SO42-/Al2O3-SnO2 catalyst in this research will have a bright future in the field of sludge production of biodiesel. (C) 2019 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available