4.8 Article

Temperature-independent thermal radiation

Publisher

NATL ACAD SCIENCES
DOI: 10.1073/pnas.1911244116

Keywords

thermal radiation; thermal emission; phase transition; quantum materials; heat transfer

Funding

  1. Office of Naval Research [N00014-16-1-2556]
  2. National Science Foundation [ECCS-1750341]
  3. Air Force Office of Scientific Research [FA9550-16-1-0159]
  4. Sandia National Laboratories
  5. US Department of Energy Office of Science Facilities [DE-SC0012704]

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Thermal emission is the process by which all objects at nonzero temperatures emit light and is well described by the Planck, Kirchhoff, and Stefan-Boltzmann laws. For most solids, the thermally emitted power increases monotonically with temperature in a one-to-one relationship that enables applications such as infrared imaging and noncontact thermometry. Here, we demonstrated ultrathin thermal emitters that violate this one-to-one relationship via the use of samarium nickel oxide (SmNiO3), a strongly correlated quantum material that undergoes a fully reversible, temperature-driven solid-state phase transition. The smooth and hysteresis-free nature of this unique insulator-to-metal phase transition enabled us to engineer the temperature dependence of emissivity to precisely cancel out the intrinsic blackbody profile described by the Stefan-Boltzmann law, for both heating and cooling. Our design results in temperature-independent thermally emitted power within the long-wave atmospheric transparency window (wavelengths of 8 to 14 mu m), across a broad temperature range of similar to 30 degrees C, centered around similar to 120 degrees C. The ability to decouple temperature and thermal emission opens a gateway for controlling the visibility of objects to infrared cameras and, more broadly, opportunities for quantum materials in controlling heat transfer.

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