Journal
POLYMER COMPOSITES
Volume 41, Issue 5, Pages 1841-1852Publisher
WILEY
DOI: 10.1002/pc.25502
Keywords
adhesion; composites; fibers
Categories
Funding
- Key Program of National Natural Science Foundation of China [51435005]
- National Key Research and Development Program of China [2016YFB0302301, 2016YFB0302302]
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In order to improve interfacial adhesion between poly(lactic acid) (PLA) and sisal fibers (SFs), bifunctional monomer bisoxazoline (BO) was introduced into melt-blending process of fibers reinforced PLA composites via in situ reactive interfacial compatibilization. The morphology of fibers and their reinforced PLA composites, thermal, and mechanical properties of the composites were studied. Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) results confirmed that PLA was successfully grafted onto the surface of fiber. BO played a hinge-like role between PLA molecular chains and SFs. The interfacial reaction and the microstructures of the SF-reinforced PLA composites were investigated by thermal analysis. The cold crystallization temperature of the composites increased by 6.5 degrees C with the addition of 0.6 wt% BO and 20 wt% SF as compared with the composites without BO. Microdebonding test further confirmed that interfacial shear strength of samples with BO increased by more than 30.7% in comparison with unmodified samples. For composites with 20 wt% SF addition, tensile strength and modulus increased by 34% and 10%, respectively, with 1 wt% BO addition. Flexural strength and modulus increased by 25% and 8%, respectively, with the addition of 1.2 wt% BO. Impact strength of 1 wt% BO-modified composites was 5.1 MPa, which is 17% higher than that of the composites without BO.
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