Stress-Measure Dependence of Phase Transformation Criterion under Finite Strains: Hierarchy of Crystal Lattice Instabilities for Homogeneous and Heterogeneous Transformations

Hierarchy of crystal lattice instabilities leading to a first-order phase transformation (PT) is found, which consists of PT instability described by the order parameter and elastic instabilities under different prescribed stress measures. After PT instability and prior to the elastic instability, an unexpected continuous third-order PT was discovered, which is followed by a first-order PT after the elastic instability. Under prescribed compressive second Piola-Kirchhoff stress, PT is third order until completion; it occurs without hysteresis and dissipation, properties that are ideal for various applications. For heterogeneous perturbations and PT, first-order PT occurs when the first elastic instability criterion (among criteria corresponding to different stress measures) is met inside the volume, surprisingly independent of the stress measure prescribed at the boundary.