Journal
PHYSICA B-CONDENSED MATTER
Volume 577, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.physb.2019.411803
Keywords
GdNbTiO6; Eu3+; Bi3+ red phosphor; Sensitization; Luminescence property; Concentration quenching; Luminescence thermal quenching
Categories
Funding
- NSFC (National Natural Science Foundation of China) [11774042, 11704056, 11104023]
- High-level personnel in Dalian innovation support program [2016RQ037]
- Scientific Research Foundation for Doctoral Program
- Natural Science Foundation of Liaoning Province [20170520097, 20180550553]
- Postgraduate Education and Teaching Reform Project of Dalian Maritime University [YJG2019210]
- Fundamental Research Funds for the Central Universities [3132019186, 3132019338]
- Open Fund of the State Key Laboratory on Integrated Optoelectronics [IOSKL2019KF06]
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Eu3+ single-doped and Eu3+, Bi3+ co-doped GdNbTiO6 phosphors were synthesized by high temperature solid-state reaction method. The crystal structure of the samples was analyzed by means of X-ray diffraction. Strong red emission at 615 nm with good color purity was observed in GdNbTiO6: Eu3+, Bi3+ system under excitations of a wide region of ultraviolet light. Investigation on Eu3+-concentration dependent luminescence of Eu3+ single-doped samples revealed that exchange interaction between Eu3+ ions was responsible for the concentration quenching of Eu3+. Efficient energy transfers from Bi3+ to Eu3+ have been proved by using the spectra. The introduction of Bi3+ effectively extended the excitation band of Eu3+ in the near-ultraviolet region. However, it almost had no effect on the line shape and peak positions of Eu3+ emission spectra. Luminescence thermal quenching behavior was observed in both Eu3+ single-doped and Eu3+, Bi3+ co-doped GdNbTiO6 phosphors, which can be ascribed to the crossover process.
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