Journal
PETROLEUM CHEMISTRY
Volume 59, Issue 12, Pages 1269-1277Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0965544119120120
Keywords
iron acetylacetonate; molybdenum acetylacetonate; nickel acetylacetonate; cobalt acetylacetonate; oil-soluble catalysts; heavy petroleum feedstock; thermocatalytic destruction
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Funding
- Government of the Russian Federation [220, 14, Z50.31.0038]
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The process of deasphalted oil thermal cracking in the presence of catalysts formed from oil-soluble Fe, Mo, Ni, and Co acetylacetonates is studied. It is shown that the used catalysts substantially change physicochemical properties of the obtained fractions. For the tested systems the structure-property relationship is ascertained and reasons behind its appearance and correlation between this relationship and process results are considered. It is found that Fe acetylacetonate (500 ppm) and Co acetylacetonate (50 and 500 ppm) show promise for further investigations.
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