Journal
ORGANIC PROCESS RESEARCH & DEVELOPMENT
Volume 24, Issue 10, Pages 1916-1926Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.9b00451
Keywords
electro-organic synthesis; flow cell; biphenol; cross-coupling; oxidation; boron-doped diamond
Categories
Funding
- Federal Ministry of Education and Research [FKZ 13XP5016D]
- DFG [Wa1276/24-1]
- Graduate School Materials Science in Mainz [GSC 266]
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The successive scale-up of electrochemical reactions is crucial with regard to the implementation of technical electro-organic syntheses. Therefore, we developed a scalable modular parallel-plate electrochemical flow cell. One distinctive feature of this flow cell is that the temperature of the electrodes can be easily controlled from the back side via an external cooling circuit, enabling high reproducibility of electrochemical conversions. Because the gap between the electrodes is kept narrow, small amounts or no supporting electrolyte is required. The practicability and performance of the novel flow cell were validated by three different anodic phenol-phenol cross-couplings as test reactions.
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