Journal
ORGANIC LETTERS
Volume 22, Issue 6, Pages 2293-2297Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00489
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Funding
- MEXT, Japan [18H04649]
- Hoansha Foundation
- Program for Leading Graduate Schools: Interactive Materials Science Cadet Program
- JSPS KAKENHI [18H01978]
- Grants-in-Aid for Scientific Research [18H01978, 18H04649] Funding Source: KAKEN
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We report on a method for the synthesis of fluorinated dibenzophospholes using triarylphosphine via dearylative annulation with an aryne. This intermolecular annulation allows the preparation of a variety of fluorinated dibenzophospholes from simple building blocks. The key to the success of this dearylative annulation is the formation of a five-coordinated tetraarylfluorophosphorane. In this work, we successfully synthesized stable tetraarylfluorophosphorane, the structure of which was unambiguously determined by X-ray crystallography.
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