Journal
ORGANIC LETTERS
Volume 22, Issue 6, Pages 2235-2239Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00433
Keywords
-
Categories
Funding
- Institute of Global Prominent Research, Chiba University
- JSPS KAKENHI [G18K14863]
Ask authors/readers for more resources
In this study, a visible-light-induced intermolecular C-H bond imidation of arenes was achieved at ambient condition. By using simple phthalimide with (diacetoxyiodo)benzene and molecular iodine, direct metal-/photocatalyst-free C-N bond formation was achieved. The imidation protocol was designed by using time-dependent density functional theory calculations and experimentally demonstrated for 28 substrates with as high as 96% yield. Mechanistic studies indicated that radical-mediated aromatic substitution occurred via photolysis of N-iodophthalimide under visible-light irradiation
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available