Journal
ORGANIC LETTERS
Volume 22, Issue 3, Pages 1124-1129Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04634
Keywords
-
Categories
Funding
- Japan Society for the Promotion of Science [17K05794]
- Grants-in-Aid for Scientific Research [17K05794] Funding Source: KAKEN
Ask authors/readers for more resources
The nickel-catalyzed hydroarylation of 1,3-dienes with arylboronic acids using a secondary homoallyl carbonate as a surrogate for the 1,3-diene and hydride source has been developed. The synthetic strategy allowed an efficient access to a wide array of hydroarylation products in high yields with high functional group compatibility without the use of an external hydride source. Mechanistic experiments indicated that the alkene-directed oxidative addition and subsequent beta-hydride elimination would be a critical process in this transformation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available