Journal
ORGANIC LETTERS
Volume 22, Issue 3, Pages 867-872Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04379
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Funding
- Junta de Castilla y Leon (European Regional Development Fund) [SA069P17]
- University of Salamanca [KCEP/463AC01]
- MINECO [CTQ2017-87529-R]
- USAL
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Using supramolecular interactions, a novel macrocyclic receptor is able to selectively extract zwitterionic phenylglycine from neutral aqueous solutions into chloroform with up to 91.8% ee. Modeling studies, nuclear magnetic resonance experiments, and X-ray diffraction analysis were carried out to explain the high enantioselectivity observed.
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