Journal
ORGANIC LETTERS
Volume 22, Issue 6, Pages 2124-2128Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04636
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Funding
- National Natural Science Foundation of China [21822303, 21772020, 2018CDXZ0002]
- Fundamental Research Funds for the Central Universities (Chongqing University)
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A three-layer chirality relay model is proposed for Rh(I)-mediated enantioselective siletane activation. A chiral ligand in the back layer controls the position of the alkyne-coordinated metal center in the middle layer, which then provides a chiral environment for the incoming substrate at the front layer. A two-dimensional contour map analysis further clarified this model.
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