Journal
ORGANIC LETTERS
Volume 22, Issue 6, Pages 2118-2123Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04607
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Funding
- National Key Research and Development Program of China [2017YFA0505903]
- National Natural Science Foundation of China [21871194, 21971169, 21572142]
- Science AMP
- Technology Department of Sichuan Province [2019YJ0160, 2019YJ0090]
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A multihydroquinone ether dialdehyde derivative 2 was incidentally obtained through an unexpected ring opening of pillar[4]arene[1]quinone 1. And the Prato reaction of 2 with [60]fullerene led to [60]fullerene bisadducts, from which trans-4 cyclic regioisomer 3 was isolated and characterized. The fulleropillar[4]arene 3 showed a larger cavity and can accommodate a viologen derivative C12V2+ with a much stronger affinity than permethyl pillar[5]arene (MP5) and pillar[4]arene[1]-quinone 1.
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