Journal
ORGANIC LETTERS
Volume 22, Issue 2, Pages 552-555Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b04315
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- Studienstiftung des deutschen Volkes
- DFG
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An efficient strategy for the synthesis of the potent phospholipase A(2) inhibitors spongidine A and D is presented. The tetracyclic core of the natural products was assembled via an intramolecular hydrogen atom transfer initiated Minisci reaction. A divergent late-stage functionalization of the tetracyclic ring system was also used to achieve a concise synthesis of petrosaspongiolide L methyl ester.
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