Journal
ORGANIC LETTERS
Volume 21, Issue 24, Pages 9950-9953Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03877
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Funding
- National Research Foundation of Korea [NRF-2015R1D1A1A01057228, NRF2019R1A2C2007825, NRF-2012M3A7B4049657, NRF-2014011165, NRF-2017R1A2B2004082]
- Chungnam National University
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Organophotocatalytic C C and C B bond formation reactions of aryl halides have been developed in the presence of an organophotosensitizer, 3,7 di ( [1,1'-bipheny1]-4-y1)-10-(4-(trifluoromethyl)pheny1)-10H-phenoxazine that has highly negative reduction potential at its photoexcited state. The developed reaction conditions are mild and allow the intermolecular C C bond formation of the generated aryl radical with electron-rich (hetero)arenes and C B bond formation with bis(pinacolato)diboron.
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