4.6 Article

Bond additivity model for anisotropic second-harmonic generation from two-dimensional honeycomb lattices

Journal

OPTICS LETTERS
Volume 45, Issue 2, Pages 268-271

Publisher

OPTICAL SOC AMER
DOI: 10.1364/OL.45.000268

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Funding

  1. National Natural Science Foundation of China [11622429]
  2. National Basic Research Program of China (973 Program) [2016YFA0300900, 2016YFA0301002]
  3. National Program for Support of Top-Notch Young Professionals [W03070062]
  4. Shu Guang Project by Shanghai Education Development Foundation [18SG02]

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We provide an analytical method for extracting detailed structural information about two-dimensional (2D) honeycomb lattices from optical second-harmonic generation (SHG) anisotropy patterns. When the lattice deviates from the ideal honeycomb structure, we relate the microscopic structural properties, such as bond length and bonding angle, to the macroscopic nonlinear susceptibility tensor based on the molecular bond additivity model. Our method will help quantitative studies of 2D materials with SHG and is readily applied to more general cases. (C) 2020 Optical Society of America

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