Journal
OPTICAL MATERIALS
Volume 100, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.optmat.2020.109670
Keywords
Red emission; Zn2SnO4 powder; Ball-milling; Phosphors powder
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Funding
- Vietnam National Foundation for Science and Technology Development (NAFOSTED) [103.03-2016.68]
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In this work, far-red-emitting Zn2SnO4 phosphor has been successfully synthesized by a facile modified solidstate reaction method from ZnO and SnO2 powders. FESEM images reveal that as-milled particles are nearly spherical, with size in the range of 10-30 rim. The particle size increases with increasing annealing temperature and it reaches the value of about 4 mu m at 1200 C. XRD patterns indicate that Zn2SnO4 phase starts occurring at similar to 700 degrees C with its single phase at 900 degrees C and the best crystalline quality of Zn2SnO4 phase is obtained at 1000 degrees C. UV-Vis spectra analysis reveals that ZnO phase reappears at high annealing temperature (>= 1100 degrees C), reflecting the deterioration of the single phase of Zn2SnO4. A broad visible band centered at 684 nm, which has never been explicitly reported, is clearly observed in the PL spectrum of the single Zn2SnO4 crystals. The intensity of this new band is influenced by annealing temperatures. It reaches the maximum value at 1000 degrees C, corresponding to the highest quality of the Zn2SnO4 phase. By using data fitting, the PL spectrum is deconvoluted into four Gaussian peaks at similar to 2.20 eV (563.5 nm), similar to 1.98 eV (626.1 nm), similar to 1.80 eV (688.8 nm), and similar to 1.68 eV (738.0 nm). The peak at similar to 2.20 eV (563.5 nm) is ascribed to oxygen vacancy (V-o) while the other emission peaks are possibly associated with a significant number of trapped states due to the high concentration of deficiencies such as oxygen vacant defects, zinc interstitials, zinc/tin vacancies (V-zn/V-sn), Zn/Sn stoichiometry or point defects.
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