Journal
MENDELEEV COMMUNICATIONS
Volume 30, Issue 1, Pages 103-105Publisher
ELSEVIER
DOI: 10.1016/j.mencom.2020.01.034
Keywords
organofluorine compounds; tosylate derivatives; X-ray studies; quantum chemical calculations; intra- and intermolecular interactions
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Funding
- Russian Science Foundation [18-73-00339]
- Ministry of Science and Higher Education of the Russian Federation
- Russian Science Foundation [18-73-00339] Funding Source: Russian Science Foundation
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Crystal structures of fluorinated alkyl tosylates TsOCH2CF2CHFCF3 and TsOCH2(CF2)(3)CHF2 have been characterized by X-ray diffraction and quantum chemical calculations. The calculations have revealed the stabilization of head-to-tail conformation for TsOCH2CHF-CF2CF3 due to intramolecular F center dot center dot center dot pi and C-H center dot center dot center dot pi interactions. Alternatively, for TsOCH2(CF2)(3)CHF2 these interactions cannot be responsible for the stabilization of head-to-tail con-formation, thus the linear conformation is proved to be more stable.
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