4.6 Article

Boron-doped graphene coated Au@SnO2 for high-performance triethylamine gas detection

Journal

MATERIALS CHEMISTRY AND PHYSICS
Volume 239, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2019.121961

Keywords

Boron-doped; Reduced graphene oxide; Heterointerface; Synergistic effect

Funding

  1. National Science Foundation of Shandong Province [ZR2017BEM049]
  2. China Postdoctoral Science Foundation [2017M612265]
  3. Startup Funding of Distinguished Professorship program [31270086963030]
  4. Shandong Provincial Science and Technology Major Project [2019GGX101029]
  5. China-Germany postdoctoral exchange program [20181032]
  6. Open Research Fund of Suzhou Institute of Nano-Tech, and Nano-Bionics [19LH01]

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Confronted with challenges in obtaining lower power consumption and higher gas response for triethylamine (TEA) gas detection, it becomes very important to rational induce heterointerface to enhance gas-sensing properties. In this work, we demonstrate that the boron-doped reduced graphene oxide (B-RGO) coated Au@SnO2 heterostructure is using as the sensor material for TEA gas detection with a response of 69.1% for 1 ppm of TEA gas at low working temperature (100 degrees C). With the wrapping of B-RGO, the response value of the Au@SnO2-based sensor for TEA detection is boosted by 5.6 times and a detection limit of ppb (parts per billion) level is achieved. The sensors are selectively sensitive to TEA gas, which is about 10 times higher than the response to the other four gases. The outstanding sensing performance is mainly attributed to the synergistic effect of the B-RGO/SnO2 and Au/SnO2 heterostructure. The present work shows that heterostructure engineering together with boron-doped graphene has excellent potential for promoting highly selective and low concentration noxious gas sensing detection.

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