Journal
MATERIALS CHEMISTRY AND PHYSICS
Volume 240, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2019.122288
Keywords
Liquid phase exfoliation; Few-layer graphene; Tannic acid; Non-covalent functionalization; Polyamide 66 fibers
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Funding
- National Key Research and Development Program of China [2016YFB0303000]
- New Materials Research Key Program of Tianjin [162XCLGX00090]
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Graphene has attracted a significant number of attentions due to the extraordinary properties. Development of a method to obtain graphene with high yield and quality is crucial for the investigations and applications of graphene. However, the large-scale fabrication of mono- and few-layer graphene sheets still remains challenges. This paper demonstrates a green and scalable one-step fabrication of single- and few-layer graphene by graphite delamination in water/tannic acid (TA) dispersion using a high-pressure homogenizer. The effect of TA concentration, homogenization pressure, and homogenization cycles on the quality and concentration of graphene dispersions were systematically investigated. The concentration of the graphene sheets (GS-TA) in TA aqueous solution reaches up to 1.16 mg/mL, with about 84% of them are fewer than five layers. Significantly, the exfoliated GS-TA is highly stable for more than 5 months. Next, for a potential application, the GS-TA/polyamide 66 composite fibers were melt-spun. The non-covalent functionalization of graphene compatibilized the interface between graphene and PA66 matrix, and increased the filler's dispersibility in the PA66 matrix. The results show similar to 118% enhancement in tensile strength of polyamide 66 nanocomposite fibers when the loading of GS-TA is 0.1 wt%. It is believed that this new green protocol for graphene production will pave the way for relatively simple industrial-scale fabrication of high-performance graphene-based nanocomposites.
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