Journal
LANGMUIR
Volume 36, Issue 12, Pages 2985-3003Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.9b03573
Keywords
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Future Energy Systems under the Canada First Research Excellence Fund (CFREF)
- Canada Foundation for Innovation (CFI)
- Alberta Advanced Education & Technology Small Equipment Grants Program (AET/SEGP)
- Canada Research Chairs Program
- National Natural Science Foundation of China [21902183]
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Hydrophobic interaction is responsible for a variety of colloidal phenomena, which also plays a key role in achieving the desired characteristics and functionalities for a wide range of interfacial applications. In this feature article, our recent advances in the quantification and modulation of hydrophobic interactions at both solid/water and air/water interfaces in different material systems have been reviewed. On the basis of surface forces apparatus (SFA) measurements of hydrophobic polymers (e.g., polystyrene), a three-regime hydrophobic interaction model that could satisfactorily encompass the hydrophobic interaction with different ranges was proposed. In addition, the atomic force microscope (AFM) coupled with various techniques such as the colloidal probe, the electrochemical process, and force mapping were employed to quantify the hydrophobic interaction from different perspectives. For the hydrophobic interactions involving deformable bubbles, the bubble probe AFM combined with reflection interference contrast microscopy (RICM) was used to simultaneously measure the interaction force and spatiotemporal evolution of the thin film drainage process between air bubbles and hydrophobized mica surfaces in an aqueous medium. The studies on the interactions of air bubbles with self-assembled monolayers (SAMs) demonstrated that the range of hydrophobic interactions does not always increase monotonically with the hydrophobicity of interacting surfaces as characterized by the static water contact angle; viz., surfaces with similar hydrophobicity can exhibit different ranges of hydrophobic interaction, while surfaces with different hydrophobicities can exhibit a similar range of hydrophobic interactions. It is found that the hydrophobic interaction can be modulated by tuning the surface nanoscale structure and chemistry. Moreover, the long-range hydrophilic attraction that resembles the hydrophobic interaction was discovered between water droplets and polyelectrolyte surfaces in an oil medium, on the basis of which polyelectrolyte coating materials were designed for oil cleaning, oil/water separation, and demulsification. The interfacial applications, remaining challenges, and future perspectives of hydrophobic interactions are discussed.
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