4.6 Article

Electro-codeposition of CeO2 nanoparticles into cobalt matrix to improve the tribocorrosion performances of Co/nano CeO2 composite layers in biological solution for medical applications

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ELSEVIER
DOI: 10.1016/j.jmbbm.2019.103443

Keywords

Cobalt; Metal matrix composites; EIS; SEM; XRD; Electrodeposited films; Fretting corrosion

Funding

  1. Research (Competences) Centre Interfaces - Tribocorrosion and Electrochemical Systems (CC-ITES) from Dunarea de Jos University of Galati
  2. Laboratoire Genie des Procedees Materiaux (LGPM) from Ecole Centrale Paris, France
  3. UEFISCDI - Ministry of Education and Research [10/30-08-2013]

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Co/nano-CeO2 composite layers were developed by electro-codeposition method from a cobalt electrolyte containing dispersed CeO2 nanoparticles. The tribocorrosion performances of both Co/nano-CeO2 and pure Co layers were comparatively investigated by sliding friction tests under lubricated condition in biological Hank solution. The effect of embedded nano-CeO2 on the corrosion electrochemical response, friction coefficient and wear loss volume is analyzed. The results show that the codeposited of nano-CeO2 particles into cobalt matrix reduce the friction coefficient and wear weight loss as well as the shift of open circuit potential to active state, increasing the polarization resistance and reducing the corrosion damages.

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