Journal
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 40, Issue 2, Pages 298-304Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2019.10.003
Keywords
Silicon nitride; Gas pressure sintering; Thermal conductivity; Nitridation process; Mechanical properties
Categories
Funding
- National Key Research and Development Program of China [2016YFB-0700300]
- National Natural Science Foundation of China [51572277, 51702340]
- Shanghai Science and Technology Committee [17YF1428800, 17ZR1434800, 17dz2307000]
- State Key Laboratory of High Performance Ceramics and Superfine Microstructure of Shanghai Institute Ceramics, Chinese Academy of Sciences
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High-purity silicon powder is used as the starting material for cost-effective preparation of silicon nitride ceramics with both high thermal conductivity and excellent mechanical properties using RE2O3 (RE= Y, La or Er) and MgO as sintering additives. Nitridation is a key procedure that would affect the properties of green bodies and the sintered samples. The beta: (alpha+beta) ratio can be increased as the samples nitrided at 1450 degrees C and a large amount of long rod-like beta-Si3N4 grains were developed in the samples. It was found that the addition of Er2O3-MgO could help to improve the mechanical properties of the sintered Si3N4 ceramics, the thermal conductivity, flexural strength and fracture toughness of the sample were 90 W/(m.K), 953 +/- 28.3 MPa and 10.64 +/- 0.61 MPa.m(1/2), respectively. The RE3+ species with larger ionic radius tended to increase the oxygen of nitrided samples and decrease N/O ratio (triangle grain boundary) of sintered samples.
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