4.8 Article

High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 10, Pages 4550-4554

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b12377

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Funding

  1. US Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division [DE-AC05-00OR22725]
  2. DOE [DE-AC05-00OR22725]

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High-entropy perovskite fluorides (HEPFs) have great potential in electrocatalysis that has not been realized because of the limitation of a high-temperature synthetic route and the limited understanding of high-entropy materials. The use of HEPFs in effective oxygen evolution catalysis and a feasible synthesis route for HEPFs in a boiled solution by combining a hydrothermal method with mechanochemistry are first reported here. These HEPFs consisting of cost-effective elements dramatically gave excellent catalytic activity for the oxygen evolution reaction in an alkaline media.

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