Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 2, Pages 1083-1089Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b12051
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Funding
- U.S. National Science Foundation EPSCoR Program [OIA-1151479]
- U.S. Department of Energy, Basic Energy Sciences [DE-SC0020272]
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Cations are crucial components in emerging functional polyelectrolytes for a myriad of applications. Rapid development in this area necessitates the exploration of new cations with advanced properties. Herein we describe a combination of computational and experimental design of cobaltocene metallo-cations that have distinct electronic and redox properties. One of the direct outcomes on the first synthesis of a complete set of cation derivatives is to discover highly stable cations, which are further integrated to construct metallo-polyelectrolytes as anion-exchange membranes in solid-state alkaline fuel cells. The device performance of these polyelectrolytes under highly basic and oxidative environments is competitive with many organo-polyelectrolytes.
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