4.8 Article Retracted Publication

被撤回的出版物: Step-Growth Annulative π-Extensio n Polymerization for Synthesis of Cove-Type Graphene Nanoribbons (Retracted article. See vol. 143, pg. 3264, 2021)

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 4, Pages 1686-1691

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b11328

Keywords

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Funding

  1. ERATO program of the JST [JPMJER1302]
  2. CREST program of the JST [JPMJCR19R1]
  3. JSPS KAKENHI [19H05463, JP26810057, JP16H00907, JP17K1955, JP18H02019]
  4. JSPS Research Fellowship for Young Scientists [18J10996]
  5. Sumitomo Foundation [141495]
  6. DAIKO Foundation
  7. World Premier International Research Center Initiative (WPI), Japan
  8. Grants-in-Aid for Scientific Research [18J10996] Funding Source: KAKEN

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Graphene nanoribbons (GNRs), nanometer-wide strips of graphene, are attracting significant attention in materials science as candidates for next-generation carbon materials. As their physical properties mainly depend on their structures, the precise synthesis of structurally well-defined GNRs is highly desirable to control their properties. Herein, we report a step-growth annulative pi-extension polymerization that allows for the rapid and modular synthesis of cove-type GNRs with pyrene and/or coronene diimide repeating units. The structures and photophysical properties of the separated GNRs were confirmed by various spectroscopic analyses. In addition, gas-blow-assisted uniform on-surface self-assembly of the GNRs was accomplished.

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