Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 3, Pages 1211-1216Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b12335
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Funding
- JSPS KAKENHI Grant [JP17H06449, JP18H01971]
- Kanazawa University SAKIGAKE project 2018
- Takeda Pharmaceutical Company Limited
- JST, PRESTO Grant [JPMJPR19T2]
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This manuscript reports a visible-light-mediated organosulfide catalysis that enables the decarboxylative coupling between simple aliphatic alcohol and tertiary or secondary alkyl carboxylic acid-derived redox active esters to produce a C(sp(3))-O-C(sp(3)) fragment. Results of the coupling using other heteroatom nucleophiles such as water, amides, and thiols are also described.
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