Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 29, Pages 12613-12619Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c00241
Keywords
-
Categories
Funding
- Northern Illinois University
- U.S. Department of Energy's Fuel Cell Technology Office
- U.S. Department of Energy, Office of Science [DE-AC02-06CH11357]
- Advanced Light Source, a DOE Office of Science User Facility [DE-AC02-05CH11231]
- Northern Illinois University's Molecular Analysis Core Facility
Ask authors/readers for more resources
The low-cost hydrogen production from water electrolysis is crucial to the deployment of sustainable hydrogen economy but is currently constrained by the lack of active and robust electrocatalysts from earth-abundant materials. We describe here an unconventional heterostructure composed of strongly coupled Ni-deficient LixNiO nanoclusters and polycrystalline Ni nanocrystals and its exceptional activities toward the hydrogen evolution reaction (HER) in aqueous electrolytes. The presence of lattice oxygen species with strong Brensted basicity is a significant feature in such heterostructure, which spontaneously split water molecules for accelerated Volmer H-OH dissociation in neutral and alkaline HER. In combination with the intimate LixNiO and Ni interfacial junctions that generate localized hotspots for promoted hydride coupling and hydrogen desorption, the catalysts produce hydrogen at a current density of 10 mA cm(-2) under overpotentials of only 20, 50, and 36 mV in acidic, neutral, and alkaline electrolytes, respectively, making them among the most active Pt-free catalysts developed thus far. In addition, such heterostructures also exhibited superior activity toward the hydrogen oxidation reaction in alkaline electrolytes.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available