Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 1, Pages 27-32Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b10436
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Funding
- PRESTO Program from the Japan Science and Technology Agency (JST) [JPMJPR17NA]
- PRESTO Program from JST [JPMJPR15N6]
- Japan Society for the Promotion of Science (JSPS) [JP16H02285]
- JSPS [17H03048, 18H04528, 17H06444, 19H00903]
- Grants-in-Aid for Scientific Research [18H04528, 17H06444, 19H00903, 17H03048] Funding Source: KAKEN
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Recently, metal-organic frameworks (MOFs) composed of sulfur secondary building units (sulfur-SBUs) have attracted significant attention as unique electronic materials with high conductivities and photo- and electrocatalytic properties. Herein we report the crystal structure of KGF-1, an example of a Pb-MOF composed of three-dimensionally extended sulfur-SBUs that displays molecular sieving behavior, visible-light absorption, and a semiconductor band structure and is a hydrogen-evolution photocatalyst.
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