Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 5, Pages 2087-2092Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b10678
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Funding
- Cornell University
- NIGMS [R35GM127135, R01GM130928]
- NSF [CHE-1531632]
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We describe a new electrophotocatalytic strategy that harnesses the power of light and electricity to generate an excited radical anion with a reducing potential of -3.2 V vs SCE, which can be used to activate substrates with very high reduction potentials (E-red approximate to -1.9 to -2.9 V). The resultant aryl radicals can be engaged in various synthetically useful transformations to furnish arylboronate, arylstannane, and biaryl products.
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