Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 282, Issue -, Pages -Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2019.121108
Keywords
Zeolitic imidazolate framework-11; Porous carbon; Iodine adsorption; Regeneration
Funding
- National Natural Science Foundation of China [21601019]
- Natural Science Foundation of Changchun Normal University [[2017]006]
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In this work, three nanoporous carbon materials Z11-700, Z11-800 and Z11-900 were synthesized by a one-step calcination of zeolitic imidazolate framework-11 (ZIF-11) at 700, 800 and 900 degrees C, respectively. The samples obtained were characterized by SEM, PXRD, FT-IR, Raman spectra and N-2 adsorption. The results showed that the three ZIF-11 derived samples were micro/mesoporous and had high BET surface areas and pore volumes. Of the synthesized samples, Z11-900 displayed an excellent iodine vapour uptake of 3775 mg/g which was superior compared with Z11-700 and Z11-800, as well as other reported solid state materials. What is more, the regeneration efficiency of Z11-900 for iodine molecules was near to 90% (3672 mg/g) after three cycles of reuse. The easy operation, highly-effective and recyclable features enable the ZIF-11 derived nanoporous carbons to be a promising adsorbent for applications in environmental remediation.
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