4.5 Article

Electrocatalytic properties of CoS2/MoS2/rGO as a non-noble dual metal electrocatalyst: The investigation of hydrogen evolution and methanol oxidation

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Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2019.109103

Keywords

CoS2/MoS2/rGO; Reduced graphene oxide; Hydrogen evolution reaction; Methanol oxidation; Direct methanol fuel cell

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A non-noble dual metal electrocatalyst based on CoS2/MoS2 embedded in reduced graphene oxide (sGO) was synthesized as an electrocatalyst for direct methanol fuel cells and hydrogen generation applications. In the methanol oxidation reaction, the CoS2/MoS2/rGO catalyst exhibited a maximum current density of 1.68 mA cm(-2) at 290 K and 2.71 mA cm(-2 ) at 310 K. In the hydrogen evolution reaction, Tafel slopes Of 48 and 86 mV dec(-1) and onset overpotentials of 90 and 160 mV were obtained for CoS2/MoS2/rGO and CoS2/MoS2, respectively. Furthermore, CoS2/MoS2/rGO as an anode catalyst in a single cell showed a maximum power density of 19 mW cm(-2) at 60 degrees C. The excellent performance of the catalyst suggests its potential for energy production. The specific surface area and edge sites of the catalyst and the presence of rGO as a conductive Material have a collective effect on the catalyst performance.

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