Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 85, Issue 5, Pages 3538-3547Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b03251
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Funding
- National Natural Science Foundation of China [21576296, 21776318, 21676302, 81703365]
- Fundamental Research Funds for Central South University [2019zzts222]
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O-Perfluoropyridin-4-yl group was first installed onto cycloketone oximes as a new electrophore, which was proven to be efficient iminyl radical precursors under photocatalytic and thermal conditions. A range of O-perfluoropyridin-4-yl oximes were successfully utilized in C(sp(2))-C(sp(3)) bond formations of quinoxalin-2(1H)-ones and alkenes, providing facile accesses to a range of functionalized alkylnitriles.
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